The reaction of hydrogen and iodine monochloride is given as :
$H_{2(g)} + 2ICl_{(g)} \rightarrow 2HCl_{(g)} + I_{2(g)}$
This reaction is of first order with respect to $H_{2(g)}$ and $ICl_{(g)}$. The following mechanisms were proposed:
Mechanism $A$ :
$H_{2(g)} + 2ICl_{(g)} \rightarrow 2HCl_{(g)} + I_{2(g)}$
Mechanism $B$ :
$H_{2(g)} + ICl_{(g)} \rightarrow HCl_{(g)} + HI_{(g)}$ ; (slow)
$HI_{(g)} + ICl_{(g)} \rightarrow HCl_{(g)} + I_{2(g)}$ ; (fast)
Which of the above mechanism$(s)$ can be consistent with the given information about the reaction?

  • A
    $A$ and $B$ both
  • B
    Neither $A$ nor $B$
  • C
    $A$ only
  • D
    $B$ only

Explore More

Similar Questions

For the reaction $A + B \rightarrow$ product,the rate of reaction is $3.6 \times 10^{-2} \ mol \ dm^{-3} \ sec^{-1}$. When $[A] = 0.2 \ mol \ dm^{-3}$ and $[B] = 0.1 \ mol \ dm^{-3}$,find the rate constant of the reaction if it is second order with respect to both reactants.

The half-life of decomposition of gaseous $CH_3CHO$ at initial pressure of $364 \ mm$ and $182 \ mm$ of $Hg$ were $440 \ sec$ and $880 \ sec$ respectively. The order of the reaction is

For the following rate law,determine the unit of the rate constant: Rate $= -\frac{d[R]}{dt} = k[A]^{\frac{1}{2}}[B]^{2}$

Difficult
View Solution

Higher order $(>3)$ reactions are rare due to

The mechanism of the reaction $2NO_{(g)} + Br_{2(g)} \rightarrow 2NOBr_{(g)}$ is given by:
$1) NO_{(g)} + Br_{2(g)} \rightleftharpoons NOBr_{2(g)}$ (fast)
$2) NOBr_{2(g)} + NO_{(g)} \rightarrow 2NOBr_{(g)}$ (slow)
If the second step is the rate-determining step,what is the order of the reaction with respect to $NO_{(g)}$?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo