The slope of the Arrhenius plot $(\ln k \, vs \, \frac{1}{T})$ of a first-order reaction is $-5 \times 10^{3} \, K$. The value of $E_{a}$ of the reaction is: (in $kJ \, mol^{-1}$)
$[\text{Given } R = 8.314 \, J \, K^{-1} \, mol^{-1}]$

  • A
    $41.5$
  • B
    $83.0$
  • C
    $166$
  • D
    $-83$

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Consider a complex reaction taking place in three steps with rate constants $k_1$,$k_2$,and $k_3$ respectively. The overall rate constant $k$ is given by the expression $k = \sqrt{\frac{k_1 k_3}{k_2}}$. If the activation energies of the three steps are $60$,$30$,and $10 \ kJ \ mol^{-1}$ respectively,then the overall energy of activation in $kJ \ mol^{-1}$ is $..........$ $(Nearest \ integer)$

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