The solubility product of a sparingly soluble $AB_2$ salt is $2.56 \times 10^{-4} \ M^3$ at $25^{\circ} C$. The $K_f$ of water is $1.8 \ K \ kg \ mol^{-1}$. The depression in freezing point of a saturated solution of $AB_2$ is (in $K$)

  • A
    $0.432$
  • B
    $0.216$
  • C
    $0.108$
  • D
    $13.824$

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$P$ and $Q$ combine to form two compounds $PQ_2$ and $PQ_3$. If $1 \ g$ of $PQ_2$ is dissolved in $51 \ g$ of benzene, the depression of freezing point is $0.8^{\circ} C$. If $1 \ g$ of $PQ_3$ is dissolved in $51 \ g$ of benzene, the depression of freezing point is $0.625^{\circ} C$. Given $K_f$ of benzene $= 5.1 \ K \ kg \ mol^{-1}$, calculate the atomic masses of $P$ and $Q$.

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