The solution of sugar in water contains

If a $1 \ m$ solution of benzoic acid in benzene has a freezing point depression of $2.56 \ ^{\circ}C$ $(K_f = 5.12 \ ^{\circ}C \ kg \ mol^{-1})$ and a boiling point elevation of $2.53 \ ^{\circ}C$ $(K_b = 2.53 \ ^{\circ}C \ kg \ mol^{-1})$,select the correct statement$(s)$:
Statement $I$: There is dimer formation when undergoing freezing.
Statement $II$: There is no change when undergoing boiling.
Statement $III$: Reverse of $I$ and $II$.
Statement $IV$: Dimer formation in freezing and boiling state.

Match the following.

$A$. Ebullioscopic constant	$I$. Depression of freezing point
$B$. Cryoscopic constant	$II$. Total pressure is the sum of partial pressures of the components
$C$. Henry's law	$III$. Elevation of boiling point
$D$. Dalton's law	$IV$. Solubility of a gas in liquid

The correct match is

On dissolving $0.5 \ g$ of a non-volatile non-ionic solute to $39 \ g$ of benzene,its vapor pressure decreases from $650 \ mm \ Hg$ to $640 \ mm \ Hg$. The depression of freezing point of benzene (in $K$) upon addition of the solute is. . . . .
(Given data : Molar mass and the molal freezing point depression constant of benzene are $78 \ g \ mol^{-1}$ and $5.12 \ K \ kg \ mol^{-1}$,respectively)

Pick the correct statement.

Assertion : Lowering of vapour pressure is directly proportional to osmotic pressure of the solution.
Reason : Osmotic pressure is a colligative property.