The species formed on fluorination of phospho | vedclass

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Question

(B) When $PCl_5$ is fluorinated in a polar organic solvent,it undergoes a reaction to form ionic species.The reaction leads to the formation of $[PCl_

Vedclass · Accepted Answer

$[PCl_4]^+[PCl_4F_2]^-$ and $[PCl_4]^+[PF_6]^-$

Vedclass · Answer

(B) When $PCl_5$ is fluorinated in a polar organic solvent,it undergoes a reaction to form ionic species.The reaction leads to the formation of $[PCl_4]^+[PCl_4F_2]^-$ (colorless crystals) and $[PCl_4]^+[PF_6]^-$ (white crystals).Thus,the correct species formed are $[PCl_4]^+[PCl_4F_2]^-$ and $[PCl_4]^+[PF_6]^-$,which corresponds to option $B$.

The species formed on fluorination of phosphorus pentachloride in a polar organic solvent are

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