The standard e.m.f. of a cell,involving one electron change,is found to be $0.591 \ V$ at $25 \ ^oC$. The equilibrium constant of the reaction is: $(F = 96,500 \ C \ mol^{-1}; R = 8.314 \ J \ K^{-1} \ mol^{-1})$

The logarithm of the equilibrium constant for the reaction $Pd^{2+}{(aq)} + 4Cl^{-}{(aq)} \rightleftharpoons PdCl_4^{2-}{(aq)}$ is (Nearest integer).
Given: $\frac{2.303 RT}{F} = 0.06 \ V$
$Pd^{2+}{(aq)} + 2e^{-} \rightleftharpoons Pd_{(s)} \quad E^{\circ} = 0.83 \ V$
$PdCl_4^{2-}{(aq)} + 2e^{-} \rightleftharpoons Pd_{(s)} + 4Cl^{-}{(aq)} \quad E^{\circ} = 0.65 \ V$

Calculate the $emf$ of the cell at $25^{\circ} C$.
Cell notation: $M | M^{2+} (0.01 \ M) || M^{2+} (0.0001 \ M) | M$
Given: $E_{cell}^{o} = 4 \ V$ and $\frac{RT}{F} \ln 10 = 0.06$. (in $V$)

For the cell $Cu_{(s)}|Cu^{2+}_{(aq)}(0.1 \ M) || Ag^{+}_{(aq)}(0.01 \ M)| Ag_{(s)}$,the cell potential $E_{1} = 0.3095 \ V$. For the cell $Cu_{(s)}|Cu^{2+}_{(aq)}(0.01 \ M) || Ag^{+}_{(aq)}(0.001 \ M)| Ag_{(s)}$,the cell potential $= ..... \times 10^{-2} \ V$. (Round off to the Nearest Integer). [Use: $\frac{2.303 \ RT}{F} = 0.059$]

One half cell in a voltaic cell is constructed by dipping a silver rod in an $AgNO_3$ solution of unknown concentration, and the other half cell is a $Zn$ rod dipped in a $1 \text{ M}$ solution of $ZnSO_4$. $A$ voltage of $1.60 \text{ V}$ is measured at $298 \text{ K}$ for this cell. What is the concentration of $Ag^+$ ions in terms of $\log x$ (where $x = [Ag^+]$)? Given: $E^\ominus_{Zn^{2+}/Zn} = -0.76 \text{ V}$, $E^\ominus_{Ag^+/Ag} = +0.80 \text{ V}$, and $\frac{2.303RT}{F} = 0.059 \text{ V}$.

Consider the cell $Pt | H_2(P_1 \ atm) | H^{+}(X_1 \ M) || H^{+}(X_2 \ M) | H_2(P_2 \ atm) | Pt$. The cell reaction will be spontaneous if