The standard enthalpy of formation $(\Delta_f H^o_{298})$ for methane,$CH_4$ is $-74.9 \ kJ \ mol^{-1}$. In order to calculate the average energy given out in the formation of a $C-H$ bond from this,it is necessary to know which one of the following?
- AThe dissociation energy of the hydrogen molecule,$H_2$
- BThe first four ionisation energies of carbon.
- CThe dissociation energy of $H_2$ and enthalpy of sublimation of carbon (graphite).
- DThe first four ionisation energies of carbon and electron affinity of hydrogen.
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Similar Questions
Consider the reaction $4NO_2(g) + O_2(g) \rightarrow 2N_2O_5(g)$, $\Delta_rH = -111 \ kJ$. If $N_2O_5(s)$ is formed instead of $N_2O_5(g)$, what will be the value of $\Delta_rH$ in $kJ$? (Given: $\Delta H_{sub} = 54 \ kJ \ mol^{-1}$ for $N_2O_5$)
Medium
View SolutionGiven the following thermochemical equations:
$(i) \ H_{2(g)} + \frac{1}{2}O_{2(g)} \rightarrow H_2O_{(l)} ; \Delta H = -68.39 \, kcal$
$(ii) \ K_{(s)} + H_2O_{(l)} + aq \rightarrow KOH_{(aq)} + \frac{1}{2}H_{2(g)} ; \Delta H = -48.0 \, kcal$
$(iii) \ KOH_{(s)} + aq \rightarrow KOH_{(aq)} ; \Delta H = -14.0 \, kcal$
Calculate the heat of formation of $KOH_{(s)}$.
$(i) \ H_{2(g)} + \frac{1}{2}O_{2(g)} \rightarrow H_2O_{(l)} ; \Delta H = -68.39 \, kcal$
$(ii) \ K_{(s)} + H_2O_{(l)} + aq \rightarrow KOH_{(aq)} + \frac{1}{2}H_{2(g)} ; \Delta H = -48.0 \, kcal$
$(iii) \ KOH_{(s)} + aq \rightarrow KOH_{(aq)} ; \Delta H = -14.0 \, kcal$
Calculate the heat of formation of $KOH_{(s)}$.
Medium
View SolutionThe enthalpies of combustion of rhombic and monoclinic sulfur are $70,960 \ cal$ and $71,030 \ cal$ respectively. The enthalpy of transition of rhombic sulfur to monoclinic sulfur is ...... $cal$.
Medium
View SolutionAt $298 \ K$,the enthalpy of fusion of a solid $(X)$ is $2.8 \ kJ \ mol^{-1}$ and the enthalpy of vaporisation of the liquid $(X)$ is $98.2 \ kJ \ mol^{-1}$. The enthalpy of sublimation of the substance $(X)$ in $kJ \ mol^{-1}$ is $.....$ (in nearest integer).
DifficultJEE MAIN 2021
View SolutionThe enthalpy of formation of ammonia is $-46.0 \ kJ \ mol^{-1}$. The enthalpy change for the reaction $2NH_{3(g)} \rightarrow N_{2(g)} + 3H_{2(g)}$ is ............... $kJ \ mol^{-1}$.
Medium
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