The standard enthalpy of formation $(\Delta_fH^o)$ at $298 \ K$ for methane,$CH_{4(g)}$ is $-74.8 \ kJ \ mol^{-1}$. The additional information required to determine the average energy for $C-H$ bond formation would be

  • A
    the first four ionization energies of carbon and electron gain enthalpy of hydrogen
  • B
    the dissociation energy of hydrogen molecule,$H_2$
  • C
    the dissociation energy of $H_2$ and enthalpy of sublimation of carbon
  • D
    latent heat of vapourization of methane

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At $1 \ bar$ and $298 \ K$,the standard molar enthalpy of formation of which substance is zero?

If the standard heat of the reaction $Fe_2O_{3(s)} + 3CO_{(g)} = 2Fe_{(s)} + 3CO_{2(g)}$ is $-6.6 \, kcal$,then $\Delta H_f^o$ for $Fe_2O_{3(s)}$ is $...... \, kcal/mol$. [Given: $\Delta H_f^o$ of $CO_{(g)} = -26.4 \, kcal$ and $\Delta H_f^o$ of $CO_{2(g)} = -94 \, kcal$]

From the following data,the heat of transition for the conversion of rhombic sulfur $(S_R)$ to monoclinic sulfur $(S_M)$ in $kJ$ is:
$S_R + O_{2(g)} \to SO_{2(g)}; \Delta H = -296.90 \ kJ$
$S_M + O_{2(g)} \to SO_{2(g)}; \Delta H = -299.40 \ kJ$

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Given the following thermochemical equations:
$(i)$ $H_{2(g)} + \frac{1}{2}O_{2(g)} \rightarrow H_2O_{(l)}; \Delta H = -285 \text{ kJ}$
$(ii)$ $N_2O_{5(g)} + H_2O_{(l)} \rightarrow 2HNO_{3(l)}; \Delta H = -76.6 \text{ kJ}$
$(iii)$ $N_{2(g)} + 3O_{2(g)} + H_{2(g)} \rightarrow 2HNO_{3(l)}; \Delta H = -348.2 \text{ kJ}$
Calculate the $\Delta H$ for the reaction: $2N_{2(g)} + 5O_{2(g)} \rightarrow 2N_2O_{5(g)}$. (in $\text{ kJ}$)

At $298 \, K$,the bond energies of $C-H, C-C, C=C$,and $H-H$ are $414, 347, 615$,and $435 \, kJ \, mol^{-1}$ respectively. What will be the enthalpy change for the reaction ${H_2}C=CH_{2(g)} + H_{2(g)} \to H_3C-CH_{3(g)}$ at $298 \, K$ in $kJ \, mol^{-1}$?

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