The values of the limiting molar conductivity $(\lambda^0)$ for $NaCl$,$HCl$ and $NaOAc$ are $126.4$,$425.9$ and $91.0 \, S \, cm^2 \, mol^{-1}$,respectively. For $HOAc$,$\Lambda^0$ in $S \, cm^2 \, mol^{-1}$ is

  • A
    $390.5$
  • B
    $299.5$
  • C
    $208.5$
  • D
    $217.4$

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Calculate the equilibrium constant for the reaction: $Cl_{2(g)} + 2I^{-}_{(aq)} \to 2Cl^{-}_{(aq)} + I_{2(s)}$
Given: $E^o_{(Cl_2|2Cl^{-})} = 1.36 \ V$ and $E^o_{(I_2|2I^{-})} = 0.536 \ V$.

The process of rusting of iron occurs as follows:
$Fe \rightarrow Fe^{2+} + 2e^{-}, E^{o} = 0.44 \ V$
$2H^{+} + 2e^{-} + \frac{1}{2} O_2 \rightarrow H_2O_{(l)}, E^{o} = 1.23 \ V$
Then for this reaction,$\Delta G^{o} = .... \ kJ/mol$

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The solubility product of $AgCl$ under standard conditions of temperature is given by

For a spontaneous reaction,the $\Delta G$,equilibrium constant $K$,and $E_{Cell}^{o}$ will be respectively:

For the reaction $4B_{(s)} + 3O_{2(g)} \rightarrow 2B_2O_{3(g)}$,the standard cell potential is $E^o_{cell} = 1.433 \ V$. Calculate the molar entropy $(S_m^o)$ of oxygen gas in $J/K \ mol$.
Given:
$(\Delta_fH^o)_{B_2O_3(g)} = -840 \ kJ/mol$
$(S_m^o)_{B_2O_3(g)} = 280 \ J/K \ mol$
$(S_m^o)_{B(s)} = 10 \ J/K \ mol$
Assume $\Delta_rG^o = -nFE^o_{cell}$ and $\Delta_rG^o = \Delta_rH^o - T\Delta_rS^o$ at $T = 298 \ K$.

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