Under the same reaction conditions,initial concentration of $1.386 \ mol \ dm^{-3}$ of a substance becomes half in $40 \ s$ and $20 \ s$ through first order and zero order kinetics,respectively. The ratio $\left(\frac{k_1}{k_0}\right)$ of the rate constants for first order $\left(k_1\right)$ and zero order $\left(k_0\right)$ of the reactions is:

The reaction of ozone with oxygen atoms in the presence of chlorine atoms can occur by a two-step process shown below:
$O_{3(g)} + Cl_{(g)}^{\bullet} \to O_{2(g)} + ClO_{(g)}^{\bullet}$ ..... $(i)$ $K_i = 5.2 \times 10^9 \ L \ mol^{-1} \ s^{-1}$
$ClO_{(g)}^{\bullet} + O_{(g)}^{\bullet} \to O_{2(g)} + Cl_{(g)}^{\bullet}$ ..... $(ii)$ $K_{ii} = 2.6 \times 10^{10} \ L \ mol^{-1} \ s^{-1}$
The closest rate constant for the overall reaction
$O_{3(g)} + O_{(g)}^{\bullet} \to 2O_{2(g)}$ is ........... $L \ mol^{-1} \ s^{-1}$

Under identical reaction conditions,for a reactant with an initial concentration of $1.386 \, M$,the time taken for the concentration to become half is $40 \, s$ for a first-order reaction and $20 \, s$ for a zero-order reaction. The ratio of the rate constant of the first-order reaction $(K_1)$ to the rate constant of the zero-order reaction $(K_0)$ is ......... $mol \, L^{-1}$.

An endothermic reaction with a high activation energy for the forward reaction is represented by the diagram:

An example of an autocatalytic reaction is:

For any chemical reaction,what factors do chemists aim to determine?