Use Hund's rule to derive the electronic configuration of $Ce^{3+}$ ion and calculate its magnetic moment on the basis of 'spin-only' formula.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(D) The atomic number of $Ce$ is $58$. The electronic configuration of $Ce$ is $[Xe] 4f^{1} 5d^{1} 6s^{2}$.
To form $Ce^{3+}$,three electrons are removed (two from $6s$ and one from $5d$ or $4f$ depending on the energy levels; for $Ce^{3+}$,the configuration is $[Xe] 4f^{1}$).
Thus,the electronic configuration of $Ce^{3+}$ is $[Xe] 4f^{1}$.
There is $n = 1$ unpaired electron in the $4f$ orbital.
The 'spin-only' magnetic moment formula is $\mu = \sqrt{n(n+2)} \ BM$.
Substituting $n = 1$:
$\mu = \sqrt{1(1+2)} = \sqrt{3} = 1.732 \ BM$.

Explore More

Similar Questions

More number of oxidation states are exhibited by the actinoids than by the lanthanoids. The main reason for this is

Which of the following $f$-block elements exhibits the highest oxidation state?

Determine whether the following statements are True $(T)$ or False $(F)$:
$(a)$ Actinoid contraction is greater than lanthanoid contraction.
$(b)$ Actinoids are elements of the $4f$ series.
$(c)$ All actinoid elements have a $7s^2$ configuration.

Difficult
View Solution

Describe the atomic and ionic radii of lanthanoids and explain lanthanoid contraction.

Which general symbol is used to represent lanthanoids?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo