What is the shape and magnetic nature of the permanganate ion $(MnO_4^-)$?

  • A
    Pyramidal,diamagnetic
  • B
    Tetrahedral,diamagnetic
  • C
    Tetrahedral,paramagnetic
  • D
    Planar,paramagnetic

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Which of the following complexes exhibits a square planar geometry?

An aqueous solution of metal ion $M1$ reacts separately with reagents $Q$ and $R$ in excess to give tetrahedral and square planar complexes,respectively. An aqueous solution of another metal ion $M2$ always forms tetrahedral complexes with these reagents. Aqueous solution of $M2$ on reaction with reagent $S$ gives a white precipitate which dissolves in excess of $S$. The reactions are summarized in the scheme given below:
$1.$ $M1$,$Q$ and $R$,respectively are :
$(A)$ $Zn^{2+}, KCN$ and $HCl$
$(B)$ $Ni^{2+}, HCl$ and $KCN$
$(C)$ $Cd^{2+}, KCN$ and $HCl$
$(D)$ $Co^{2+}, HCl$ and $KCN$
$2.$ Reagent $S$ is :
$(A)$ $K_4[Fe(CN)_6]$
$(B)$ $Na_2HPO_4$
$(C)$ $K_2CrO_4$
$(D)$ $KOH$
Give the answer for question $1$ and $2$.

$[FeF_6]^{3-}$ has $Fe$ atom . . . . . . hybridised with unpaired . . . . . . electrons.

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