What is the slope of the straight line for the graph drawn between $\ln k$ and $\frac{1}{T}$,where $k$ is the rate constant of a reaction at temperature $T$?

  • A
    $\frac{-E_a}{2.303 R}$
  • B
    $\frac{-E_a}{R}$
  • C
    $\frac{E_a}{R}$
  • D
    $\frac{R}{E_a}$

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$A$ reaction takes place in three steps with individual rate constants and activation energies. The overall rate constant is given by $k = (\frac{k_1 k_2}{k_3})^{2/3}$. The overall activation energy of the reaction in $kJ/mol$ is:
$Step$ $Rate\ Constant\ /\ Activation\ energy$
$Step\ 1$ $k_1, E_{a_1} = 180\ kJ/mol$
$Step\ 2$ $k_2, E_{a_2} = 80\ kJ/mol$
$Step\ 3$ $k_3, E_{a_3} = 50\ kJ/mol$

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For the decomposition reaction of $N_2O_5$,the slope of the graph of $\log K$ versus $1/T$ is $-1.2 \times 10^4 \ K$. Calculate the activation energy $(E_a)$ of the reaction.

Explain the rate of reaction with energy of activation and temperature with the help of the Arrhenius equation and state its importance.

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