When $NaCl$ (molten) is doped with $10^{-5} \, mol \, \%$ of $AlCl_3$,what is the concentration of cation vacancies?

  • A
    $6.02 \times 10^{16} \, mol^{-1}$
  • B
    $12.04 \times 10^{17} \, mol^{-1}$
  • C
    $6.02 \times 10^{17} \, mol^{-1}$
  • D
    $12.04 \times 10^{16} \, mol^{-1}$

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$(1)$ Frenkel defect is favored by small difference in the sizes of cation and anion.
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Analysis of the density of an electrically neutral $NaCl$ crystal containing vacancies yielded the following results:
$(i)$ Density of $NaCl$ crystal with all sites occupied $= 2.178 \times 10^3 \ kg \ m^{-3}$
$(ii)$ Density of $NaCl$ crystal with vacancies $= 2.165 \times 10^3 \ kg \ m^{-3}$
Then the percentage of vacancies in the $NaCl$ crystal is .....

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