When $50 \ cm^3$ of $0.2 \ N \ H_2SO_4$ is mixed with $50 \ cm^3$ of $1 \ N \ KOH$,the heat liberated is

  • A
    $11.46 \ kJ$
  • B
    $57.3 \ kJ$
  • C
    $573 \ kJ$
  • D
    $573 \ J$

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An ideal gas is allowed to expand both reversibly and irreversibly in an isolated system. If $T_i$ is the initial temperature and $T_f$ is the final temperature,which of the following statements is correct?

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$A$ sample of argon at $1 \text{ atm}$ pressure and $300 \text{ K}$ expands reversibly and adiabatically from $1.25 \text{ dm}^3$ to $2.5 \text{ dm}^3$. Calculate the approximate enthalpy change (in $\text{J}$).
$(I)$ $C_V$ for argon is $12.48 \text{ J K}^{-1} \text{ mol}^{-1}$
$(II)$ Assume argon to be an ideal gas
$(III)$ $\Delta T = 111.5 \text{ K}$ (temperature decrease)

$6 \ g$ of graphite is burnt in a bomb calorimeter at $25^{\circ} C$ and $1 \ atm$ pressure. The temperature of water increased from $25^{\circ} C$ to $31^{\circ} C$. If $\Delta H$ of this reaction is $-248 \ kJ \ mol^{-1}$,find out $C_V$ (in $kJ \ K^{-1}$) of the bomb calorimeter.

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