When silver nitrate is heated to red hot,what is formed?

In chloro-alkali industries,during the Solvay ammonia process,a redox change occurs during:

Assign $A, B, C, D$ for the given type of reaction: $CuSO_4$ (solution) + $ZnCl_2$ (solution) $\longrightarrow$ No reaction.

Which of the following reactions are redox reactions?
$I. \, Cr_2O_7^{2-} + 2OH^- \to 2CrO_4^{2-} + H_2O$
$II. \, Zn + CuSO_4 \to ZnSO_4 + Cu$
$III. \, 2MnO_4^- + 3Mn^{2+} + 4OH^- \to 5MnO_2 + 2H_2O$
$IV. \, 2Cu^+ \to Cu + Cu^{2+}$

Match the reactions in Column $I$ with the nature of the reactions/type of the products in Column $II$.

Column $I$	Column $II$
$A$. $O_2^{-} \rightarrow O_2 + O_2^{2-}$	$p$. redox reaction
$B$. $CrO_4^{2-} + H^{+} \rightarrow$	$q$. one of the products has trigonal planar structure
$C$. $MnO_4^{-} + NO_2^{-} + H^{+} \rightarrow$	$r$. dimeric bridged tetrahedral metal ion
$D$. $NO_3^{-} + H_2SO_4 + Fe^{2+} \rightarrow$	$s$. disproportionation

For the reaction: $4Fe + 3O_2 \rightleftharpoons 4Fe^{3+} + 6O^{2-}$,which of the following statements is $NOT$ correct?