Which among the following reactions is favoured in the forward direction by an increase in temperature?

  • A
    $N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)} + 22.9 \ kcal$
  • B
    $N_{2(g)} + O_{2(g)} \rightleftharpoons 2NO_{(g)} - 42.8 \ kcal$
  • C
    $2SO_{2(g)} + O_{2(g)} \rightleftharpoons 2SO_{3(g)} + 45.3 \ kcal$
  • D
    $H_{2(g)} + Cl_{2(g)} - 44 \ kcal \rightleftharpoons 2HCl_{(g)}$

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In which of the following reactions at equilibrium,the position of the equilibrium shifts towards the products,if the total pressure is increased?
$(I)$ $X_{2(g)} + 3Y_{2(g)} \rightleftharpoons 2XY_{3(g)}$
$(II)$ $X_{2(g)} + Y_{2(g)} \rightleftharpoons 2XY_{(g)}$
$(III)$ $X_{2(g)} + Z_{2(g)} \rightleftharpoons 2XZ_{(g)}$
$(IV)$ $X_{2(g)} + Y_{4(g)} \rightleftharpoons 2XY_{2(g)}$

For the reaction $CO_{(g)} + H_2O_{(g)} \rightleftharpoons CO_{2(g)} + H_{2(g)}$,the equilibrium amount of $CO_{2(g)}$ increases by:

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