Which buffer solution out of the following will have $pH > 7$?

Which of the following is a buffer solution?

$20 \ mL$ solution contains $0.1 \ M \ NH_4Cl$ and $0.01 \ M \ NH_4OH$. By adding which one will its $pH$ not change?

$A$ weak acid of dissociation constant $10^{-5}$ is being titrated with aqueous $NaOH$ solution. The $pH$ at the point of one-third neutralization of the acid will be:-

$A$ student needs to prepare a buffer solution of propanoic acid and its sodium salt with $pH$ $4$. The ratio of $\frac{[CH_{3}CH_{2}COO^{-}]}{[CH_{3}CH_{2}COOH]}$ required to make the buffer is .....
Given: $K_{a}(CH_{3}CH_{2}COOH) = 1.3 \times 10^{-5}$

The $pH$ of a simple sodium acetate buffer is given by $pH = pK_a + \log \frac{[Salt]}{[Acid]}$. $K_a$ of acetic acid $= 1.8 \times 10^{-5}$. If $[Salt] = [Acid] = 0.1 \, M$,the $pH$ of the solution would be about