Which of the following complexes gives only 2 | vedclass

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(C) The reaction with $AgNO_3$ precipitates only the ionizable $Cl^-$ ions present outside the coordination sphere.For $25\%$ mole of $AgCl$ to be for

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$PtCl_4 \cdot 4NH_3$

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(C) The reaction with $AgNO_3$ precipitates only the ionizable $Cl^-$ ions present outside the coordination sphere.For $25\%$ mole of $AgCl$ to be formed from $1$ mole of the complex,there must be $1$ ionizable $Cl^-$ ion out of $4$ total $Cl^-$ atoms.This corresponds to the formula $[Pt(NH_3)_4Cl_3]Cl$,which is represented by $PtCl_4 \cdot 4NH_3$.Thus,$PtCl_4 \cdot 4NH_3$ dissociates as $[Pt(NH_3)_4Cl_3]^+ + Cl^-$,yielding $1$ mole of $AgCl$ per mole of complex.

Which of the following complexes gives only $25\%$ mole of $AgCl$ precipitate when reacted with excess $AgNO_3$?

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