Which is the most suitable reagent for the following conversion?
$CH_3-CH=CH-CH_2-CO-CH_3 \rightarrow CH_3-CH=CH-CH_2-COOH$

  • A
    Tollen's reagent
  • B
    Benzoyl peroxide
  • C
    $I_2$ and $NaOH$ solution with subsequent acidification
  • D
    $Sn$ and $NaOH$ solution

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Which is not true about acetophenone?

Match the examples given in Column $I$ with the name of the reaction in Column $II$ and identify the correct matches.
Column $I$ $(Example)$ Column $II$ $(Reaction)$
$a$. $CH_3COCl + H_2 \xrightarrow{Pd-C/BaSO_4} CH_3CHO$ Stephen's reaction
$b$. $C_6H_5CHO \xrightarrow{NaOH, \Delta} C_6H_5CH_2OH + C_6H_5COO^-Na^+$ Cannizzaro's reaction
$c$. $C_6H_6 + CH_3COCl \xrightarrow{AlCl_3} C_6H_5COCH_3$ Friedel-Crafts acylation
$d$. $R-CH_2-COOH \xrightarrow[H_2O]{Br_2/Red P} R-CH(Br)-COOH$ $HVZ$ reaction
$e$. $CH_3-CN \xrightarrow[\text{(ii) } H_2O/H^+]{\text{(i) } SnCl_2/HCl} CH_3CHO$ Stephen's reaction
$f$. $2 CH_3CHO \xrightarrow[\Delta]{NaOH} CH_3-CH=CHCHO$ Aldol condensation

Least reactive towards nucleophilic addition is

Find the major product of the following reaction:
$Ph-CHO + CH_3-CHO \xrightarrow[\Delta]{Ca(OH)_2}$ Major product

$H-CDO + H^{18}O^{-} \rightarrow D-C^{18}O^{-} + CH_2D-OH$. The above reaction is known as:

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