Which metal among the following is most sensitive towards oxidation?

  • A
    $Fe$
  • B
    $Cr$
  • C
    $Ca$
  • D
    $Al$

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The oxidation potentials of $Zn, Cu, Ag, H_2$ and $Ni$ are $0.76, -0.34, -0.80, 0$ and $0.25 \ V$ respectively. Which reaction provides the maximum voltage?

Give the symbolic representation of the following half-cells (electrodes):
$(i)$ $2H^{+}_{(aq)} + 2e^- \to H_{2_{(g)}}$
$(ii)$ $Br_{2_{(aq)}} + 2e^- \to 2Br^{-}_{(aq)}$
$(iii)$ $2Br^{-}_{(aq)} \to Br_{2_{(aq)}} + 2e^-$

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$E^o_{cell}$ for the cell: $Pt_{(s)} | H_{2(g)} | HCOOH_{(aq)} || CH_3COOH_{(aq)} | H_{2(g)} | Pt_{(s)}$ at $25^oC$ is ............ $V$. ($K_a$ of $HCOOH = 2.4 \times 10^{-4}$,$K_a$ of $CH_3COOH = 1.8 \times 10^{-5}$,$\log 2 = 0.3$,$\log 3 = 0.477$,$\frac{2.303RT}{F} = 0.059$ or $0.06$)

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Discuss the method to determine the cell potential of any cell when a standard hydrogen electrode is considered as the anode,with a suitable example.

For the reduction of $NO_3^{-}$ ion in an aqueous solution,$E^0$ is $+0.96 \ V$. Values of $E^0$ for some metal ions are given below:
$V^{2+}_{(aq)} + 2e^{-} \rightarrow V \ \ \ \ E^0 = -1.19 \ V$
$Fe^{3+}_{(aq)} + 3e^{-} \rightarrow Fe \ \ \ \ E^0 = -0.04 \ V$
$Au^{3+}_{(aq)} + 3e^{-} \rightarrow Au \ \ \ \ E^0 = +1.40 \ V$
$Hg^{2+}_{(aq)} + 2e^{-} \rightarrow Hg \ \ \ \ E^0 = +0.86 \ V$
The pair$(s)$ of metals that is(are) oxidized by $NO_3^{-}$ in aqueous solution is(are):
$(A) V$ and $Hg$
$(B) Hg$ and $Fe$
$(C) Fe$ and $Au$
$(D) Fe$ and $V$

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