Which of the following aldehydes is most reac | vedclass

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(C) The reactivity of carbonyl compounds towards nucleophilic addition reactions depends on the magnitude of the positive charge on the carbonyl carbo

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$HCHO$

Vedclass · Answer

(C) The reactivity of carbonyl compounds towards nucleophilic addition reactions depends on the magnitude of the positive charge on the carbonyl carbon atom.Alkyl groups are electron-donating ($+I$ effect),which decreases the positive charge on the carbonyl carbon and reduces its reactivity.In $HCHO$ (formaldehyde),there are no alkyl groups attached to the carbonyl carbon.In $CH_3CHO$ (acetaldehyde),one methyl group is attached.In $C_6H_5CHO$ (benzaldehyde),the phenyl group provides resonance stabilization,further reducing the electrophilicity of the carbonyl carbon.Therefore,the order of reactivity is $HCHO > CH_3CHO > C_6H_5CHO$.Thus,$HCHO$ is the most reactive.

Which of the following aldehydes is most reactive $?$

Similar Questions

Which of the following reactions is not an example of a nucleophilic addition-elimination reaction?

Identify the product $A$ in the following reaction:
$\text{Substrate} \xrightarrow{MnO_2} A$
(The substrate is a benzene ring with a $-OH$ group,a $-COOH$ group,and a $-CH(CH_2CH_3)CHO$ group attached to it.)

Which of the following is the product of aldol condensation?

In the following reaction, the major product $(H)$ is

Assertion : Benzaldehyde is more reactive than ethanol towards nucleophilic attack.
Reason : The overall effect of $-I$ and $+R$ effect of phenyl group decreases the electron density on the carbon atom of $>C=O$ group in benzaldehyde.

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