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When do positive and negative charges appear on a carbon atom? Give examples.

The intermediates in heteropolar reactions are

Which of the following compounds gives the most stable carbocation upon dehydrogenation?

The stability of carbanions follows the order:
$I: CH_3CH_2CH_2\bar{C}H_2$
$II: CH_3\bar{C}HCH_2CH_3$
$III: (CH_3)_3\bar{C}$
$IV: CH_3\bar{C}(Ph)CH_2CH_3$

List the reactive intermediates produced by the fission of a covalent bond and describe their main characteristics.

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