Which of the following combinations of reagents does not undergo a redox reaction in an aqueous medium?

Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$Na_3PO_4 + Fe_2(SO_4)_3 \longrightarrow FePO_4 \downarrow + Na_2SO_4$

Which of the following are non-metal displacement reactions?
$(A)$ $Ca_{(s)} + 2 H_2 O_{(l)} \longrightarrow Ca(OH)_{2(aq)} + H_{2(g)}$
$(B)$ $V_2 O_{5(s)} + 5 Ca_{(s)} \stackrel{\Delta}{\longrightarrow} 2 V_{(s)} + 5 CaO_{(s)}$
$(C)$ $2 Fe_{(s)} + 3 H_2 O_{(g)} \stackrel{\Delta}{\longrightarrow} Fe_2 O_{3(s)} + 3 H_{2(g)}$
$(D)$ $Cr_2 O_{3(s)} + 2 Al_{(s)} \stackrel{\Delta}{\longrightarrow} Al_2 O_{3(s)} + 2 Cr_{(s)}$

In which of the following conversions does a blue colour appear?

$20 \, mL$ of $0.02 \, M \, K_2Cr_2O_7$ solution is used for the titration of $10 \, mL$ of $Fe^{2+}$ solution in the acidic medium. The molarity of $Fe^{2+}$ solution is ........... $\times 10^{-2} \, M$ (Nearest Integer).

$Na_2S_2O_3$ is