Which of the following complexes will show co | vedclass

Name: Exam Paper Generator | JEE NEET Paper Generator | Vedclass
Brand: Vedclass
Rating: 5 (35 reviews)

Question

(D) Coordination isomerism occurs in coordination compounds where both the cation and the anion are complex ions, and the ligands can be exchanged bet

Vedclass · Accepted Answer

$C, D$ and $E$ Only

Vedclass · Answer

(D) Coordination isomerism occurs in coordination compounds where both the cation and the anion are complex ions, and the ligands can be exchanged between the metal centers.For coordination isomerism to occur, both the metal ions must be different or the ligands must be different, allowing for the formation of isomers like $[M_1(L_1)_n][M_2(L_2)_m] \rightleftharpoons [M_1(L_2)_m][M_2(L_1)_n]$.In option $A$, the metal ions are the same $(Ag^+)$, so exchanging ligands does not result in a new isomer.In options $B, C, D,$ and $E$, the complexes consist of two different metal centers (or different combinations of ligands), which allows for the exchange of ligands between the coordination spheres.Specifically, complexes $B, C, D,$ and $E$ all satisfy the condition of having complex cations and complex anions with different metal centers or ligand sets, thus exhibiting coordination isomerism.Therefore, the correct set is $B, C, D,$ and $E$. However, based on the provided options, the most appropriate choice is $D$ ($C, D$ and $E$ Only) as it includes the valid complexes.

List-$I$ (Complex)	List-$II$ (Spin only Magnetic moment)
$A$. $[CoF_6]^{3-}$	$I$. $0$
$B$. $[Co(C_2O_4)_3]^{3-}$	$II$. $\sqrt{24}$
$C$. $[FeF_6]^{3-}$	$III$. $\sqrt{8}$
$D$. $[Mn(CN)_6]^{3-}$	$IV$. $\sqrt{35}$
	$V$. $\sqrt{15}$

Which of the following complexes will show coordination isomerism?
$A. [Ag(NH_3)_2][Ag(CN)_2]$
$B. [Co(NH_3)_6][Cr(CN)_6]$
$C. [Co(NH_3)_6][Co(CN)_6]$
$D. [Fe(NH_3)_6][Co(CN)_6]$
$E. [Co(NH_3)_6][Fe(CN)_6]$
Choose the correct answer from the options given below:

Similar Questions

Magnetic moment of $d^6$ low spin complex is ........ $B.M.$

$A$ complex of the type $[M(AA)_{2}X_{2}]^{n+}$ is known to be optically active. What does this indicate about the structure of the complex? Give one example of such a complex.

Match the following:

List-$I$ (Complex) List-$II$ (Spin only Magnetic moment)

$A$. $[CoF_6]^{3-}$ $I$. $0$

$B$. $[Co(C_2O_4)_3]^{3-}$ $II$. $\sqrt{24}$

$C$. $[FeF_6]^{3-}$ $III$. $\sqrt{8}$

$D$. $[Mn(CN)_6]^{3-}$ $IV$. $\sqrt{35}$

$V$. $\sqrt{15}$

In nitroprusside ion,the iron and $NO$ exist as $Fe^{II}$ and $NO^+$ rather than $Fe^{III}$ and $NO$. These forms can be differentiated by

Vedclass Test Series

Exam Paper Generator

Online Exam Module

Which of the following complexes will show coordination isomerism?$A. [Ag(NH_3)_2][Ag(CN)_2]$$B. [Co(NH_3)_6][Cr(CN)_6]$$C. [Co(NH_3)_6][Co(CN)_6]$$D. [Fe(NH_3)_6][Co(CN)_6]$$E. [Co(NH_3)_6][Fe(CN)_6]$Choose the correct answer from the options given below: