Which of the following compounds will not give a positive chromyl chloride test?

The pair$(s)$ of ions where $BOTH$ the ions are precipitated upon passing $H_2S$ gas in the presence of dilute $HCl$,is(are):
$(A) Ba^{2+}, Zn^{2+}$
$(B) Bi^{3+}, Fe^{3+}$
$(C) Cu^{2+}, Pb^{2+}$
$(D) Hg^{2+}, Bi^{3+}$

$A$ solution contains $Cl^{-}$,$I^{-}$,and $SO_{4}^{2-}$ ions. Which of the following ions is capable of precipitating all of the above when added to this solution?

In the group $III$ radicals,in place of $NH_4Cl$,which of the following can be used?

$(T)$ imparts violet colour $\xrightarrow{compd.\,(U) + conc.\,H_2SO_4}$ $(V)$ Red gas $\xrightarrow{NaOH + AgNO_3}$ $(W)$ Red ppt. $\xrightarrow{NH_3\,soln.}$ $(X)$
$(W)$ Red ppt. $\xrightarrow{dil.\,HCl}$ $(Y)$ white ppt.
$(U)$ $\xrightarrow[\Delta]{NaOH}$ $(Z)$ gas (gives white fumes with $HCl$)?
$(T)$ sublimes on heating
Identify $(T)$ to $(Z).$

The only cations present in a slightly acidic solution are $Fe^{3+}$,$Zn^{2+}$,and $Cu^{2+}$. The reagent that when added in excess to this solution would identify and separate $Fe^{3+}$ in one step is