Which of the following compounds will undergo racemisation when hydrolysed by an aqueous $KOH$ solution?
$(i)$ $C_6H_5CH_2Cl$
$(ii)$ $CH_3CH_2CH_2Cl$
$(iii)$ $(CH_3)_2CHCH_2Cl$
$(iv)$ $CH_3CH(Cl)C_2H_5$

$C_6H_6 + CH_3CH_2CH_2Cl + AlCl_3 \to X$ (Major product)
$X$ (Major product) $\xrightarrow{HNO_3 + H_2SO_4} Y$ (Major product) $\xrightarrow{Sn + HCl} Z$ $\xrightarrow{H_2SO_4 + SO_3} W$
$W$ is

Two bottles containing $C_6H_5I$ and $C_6H_5CH_2I$ have lost their original labels. They are labeled as $A$ and $B$ for testing. $A$ and $B$ are taken separately in test tubes and boiled with $NaOH$ solution. The final solution of each test tube is acidified with dilute $HNO_3$ and a little $AgNO_3$ is added. Solution $B$ gives a yellow precipitate. Which of the following statements is correct?

Which of the following is the most reactive towards $S_{N}1$ mechanism?

$A$ solution of $(+)-1$-chloro-$1$-phenylethane in toluene racemizes slowly in the presence of a small amount of $SbCl_5$ due to the formation of which of the following?

Which of the following haloalkanes would undergo $S_{N}2$ reaction at the fastest rate?