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(C) The peroxide effect (Kharasch effect) is only observed with $HBr$. $HCl$ and $HI$ do not show the peroxide effect because the $H-Cl$ bond is too s

Vedclass · Accepted Answer

$CH_3-CH=CH_2 \xrightarrow[R_2O_2]{HCl} CH_3-CH_2-CH_2-Cl$

Vedclass · Answer

(C) The peroxide effect (Kharasch effect) is only observed with $HBr$. $HCl$ and $HI$ do not show the peroxide effect because the $H-Cl$ bond is too strong for the radical chain propagation step,and the addition of $I\cdot$ to the alkene is endothermic. Therefore,$HCl$ adds to propene according to Markovnikov's rule to give $2$-chloropropane $(CH_3-CHCl-CH_3)$,making the product in option $(c)$ incorrect.

Which of the following obtained products is not correct?

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