Which of the following orders is not correct?

  • A
    $[Co(H_2O)_6]^{+2} < [Fe(H_2O)_6]^{+3} < [Fe(CN)_6]^{-3}$ ($\Delta_0$ order)
  • B
    $[Fe(CN)_6]^{-4} > [Fe(CN)_6]^{-3}$ ($Fe-C$ bond length)
  • C
    $CN^- < CO$ ($\pi$-accepting tendency)
  • D
    $C_2H_4 > K[PtCl_3(C_2H_4)]$ ($C-C$ bond length)

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Give the correct order of initials $T$ or $F$ for following statements. Use $T$ if statement is true and $F$ if it is false.
$(I)$ Sulphide ions react with $Na_2[Fe(CN)_5(NO)]$ to form a purple coloured compound $Na_4[Fe(CN)_5(NOS)]$. In the reaction,the oxidation state of iron changes.
$(II)$ $Pt(IV)$ compounds are relatively more stable than $Ni(IV)$ compounds.
$(III)$ The welding of magnesium can be done in the atmosphere of Helium.
$(IV)$ $LiAlH_4$ on hydrolysis will give $H_2$.

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Match the following complexes in List-$I$ with their colors in List-$II$:
List-$I$ (Complex)List-$II$ (Color)
$A. [Ni(en)_3]^{2+}$$I. \text{Green}$
$B. [Ni(H_2O)_4(en)]^{2+}$$II. \text{Blue}$
$C. [Ni(H_2O)_6]^{2+}$$III. \text{Pale blue}$
$D. [Ni(H_2O)_2(en)_2]^{2+}$$IV. \text{Violet}$

Among the statements $(a)-(d)$,the incorrect ones are:
$(a)$ Octahedral $Co(III)$ complexes with strong field ligands have very high magnetic moments.
$(b)$ When $\Delta_{0} < P$,the $d-$electron configuration of $Co(III)$ in an octahedral complex is $t_{2g}^{4} e_{g}^{2}$.
$(c)$ Wavelength of light absorbed by $[Co(en)_{3}]^{3+}$ is lower than that of $[CoF_{6}]^{3-}$.
$(d)$ If the $\Delta_{0}$ for an octahedral complex of $Co(III)$ is $18,000 \ cm^{-1}$,the $\Delta_{t}$ for its tetrahedral complex with the same ligand will be $16,000 \ cm^{-1}$.

The complex ion $[Co(en)_2Br_2]^+$ has two optical isomers. Their correct configurations are:

Which of the following has a yellow colour?

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