Which of the following pairs of compounds do not exist?

Give examples and suggest reasons for the following features of the transition metal chemistry:
$(i)$ The lowest oxide of transition metal is basic,the highest is amphoteric/acidic.
$(ii)$ $A$ transition metal exhibits highest oxidation state in oxides and fluorides.
$(iii)$ The highest oxidation state is exhibited in oxoanions of a metal.

Fill in the blanks:
$(a)$ The only $Mn$ halide compound that shows an oxidation state of $+7$ is ........
$(b)$ The $E^{\ominus}_{M^{II}/M}$ value is maximum negative for ........ in the $3d$ series.
$(c)$ Between $Cr^{2+}$ and $Fe^{2+}$,the stronger reducing agent is ........

Among $K, Ca, Fe,$ and $Zn$,the element which can form more than one binary compound with chlorine is

Which of the following metal oxides is not amphoteric?

$(a)$ Transition metals can act as catalysts because they can change their oxidation state. How does $Fe(III)$ catalyze the reaction between iodide and persulphate ions?
$(b)$ Mention any three processes where transition metals act as catalysts.