Which of the following sets of quantum numbers is not correct?

Which of the following sets of quantum numbers is not valid?

The quantum numbers of six electrons are given below. Arrange them in order of increasing energy. If any of these combinations have the same energy,list them:
$(1)$ $n = 4, l = 2, m_l = 2, m_s = -1/2$
$(2)$ $n = 3, l = 2, m_l = 1, m_s = +1/2$
$(3)$ $n = 4, l = 1, m_l = 0, m_s = +1/2$
$(4)$ $n = 3, l = 2, m_l = -2, m_s = -1/2$
$(5)$ $n = 3, l = 1, m_l = -1, m_s = +1/2$
$(6)$ $n = 4, l = 1, m_l = 0, m_s = +1/2$

Which is the correct order of increasing energy of the listed orbitals in the atom of titanium? (At. no. $Z = 22$)

An $e^-$ has a magnetic quantum number $(m_l)$ of $-3$. What is the minimum possible principal quantum number $(n)$ for this electron?

If the given four electronic configurations:
$(i)$ $n=4, l=1$
$(ii)$ $n=4, l=0$
$(iii)$ $n=3, l=2$
$(iv)$ $n=3, l=1$
are arranged in order of increasing energy, then the order will be: