Which of the following solutions exhibits the minimum boiling point elevation under identical conditions? (Assume complete dissociation)

Identify the correct statement from the following.

The freezing point of an aqueous solution which contains $5\%$ by mass urea,$1.0\%$ by mass $KCl$,and $10\%$ by mass glucose is ........ $K$. $\left( K_f(H_2O) = 1.86 \ K \ kg \ mol^{-1} \right)$

Determine the expected value of $\Delta T_{f}$ for $1 \ m$ $CaCl_{2}$ solution if $1 \ m$ urea solution has $\Delta T_{f}$ value '$x$' $K$.

Solutions $A$,$B$,$C$ and $D$ are respectively $0.1 \ M$ glucose,$0.05 \ M \ NaCl$,$0.05 \ M \ BaCl_{2}$ and $0.1 \ M \ AlCl_{3}$. Which one of the following pairs is isotonic?

The elevation of boiling point of $0.10 \ m$ aqueous $CrCl_{3} \cdot xNH_{3}$ solution is two times that of $0.05 \ m$ aqueous $CaCl_{2}$ solution. The value of $x$ is.........
[Assume $100 \%$ ionisation of the complex and $CaCl_{2},$ coordination number of $Cr$ as $6,$ and that all $NH_{3}$ molecules are present inside the coordination sphere $]$