Which of the following species is (are) desirable substance$(s)$ in the extraction of copper but not in the extraction of iron?

Which of the following is an incorrect match?

Consider the following metallurgical processes:
$I$. Heating impure metal with $CO$ and distilling the resulting volatile carbonyl (b.p. $43 \ ^oC$) and finally decomposition at $150 \ ^oC - 200 \ ^oC$ to get the pure metal.
$II$. Heating the sulphide ore in air until a part is converted to oxide and then further heating in the absence of air to let the oxide react with unchanged metal sulphide.
$III$. Electrolysis of the molten electrolyte containing approximately equal amounts of the metal chloride and $NaCl$ to obtain the metal.
The processes used for obtaining magnesium,nickel and copper are respectively:

Spiegeleisen is an alloy of

What is Thomas slag?

The process of the extraction of copper from copper pyrites involves:-
$(I)$ Froth floatation $(II)$ Calcination $(III)$ Roasting $(IV)$ Self reduction $(V)$ Smelting $(VI)$ Liquation $(VII)$ Electrorefining