Which of the following statements is not true?

The number of primary,secondary,and tertiary amines possible with the molecular formula $C_3H_9N$ is:

What does the molecular formula $C_3H_9N$ represent?

Consider the following sequence of reactions:
Chlorobenzene $\xrightarrow[ii) CO_2, H_3O^{+}]{i) Mg, \text{dry ether}} \text{Benzoic acid}$ $\xrightarrow{NH_3, \Delta} \text{Benzamide (A)}$ $\xrightarrow{Br_2, NaOH} \text{Aniline (B)}$
$11.25 \ mg$ of chlorobenzene will produce $.......... \times 10^{-1} \ mg$ of product $B$.
(Consider the reactions result in complete conversion.)
[Given molar mass of $C, H, O, N$ and $Cl$ as $12, 1, 16, 14$ and $35.5 \ g \ mol^{-1}$ respectively]

Consider the following reaction sequence starting from $p$-nitrotoluene:
$(i)$ $\text{Sn/HCl; OH}^-$
(ii) $(\text{CH}_3\text{CO})_2\text{O}$
(iii) $\text{Br}_2/\text{AlBr}_3$
(iv) $\text{H}_3\text{O}^+$
When the final product $(P)$ is subjected to Carius analysis using $\text{AgNO}_3$, $1.0 \text{ g}$ of the product $(P)$ will produce . . . . . . $\text{g}$ of the precipitate of $\text{AgBr}$. (Nearest Integer)
(Given: molar mass in $\text{g mol}^{-1}$: $\text{C} = 12, \text{H} = 1, \text{O} = 16, \text{N} = 14, \text{Br} = 80, \text{Ag} = 108$)

Match the following:

List-$I$	List-$II$
$A$. Amide	$I$. Carbylamine reaction
$B$. Nitrile	$II$. Hinsberg's reagent
$C$. $C_6H_5SO_2Cl$	$III$. Hofmann's bromamide reaction
$D$. $1^{\circ}$-Amine	$IV$. $LiAlH_4$