Which of the following statements is correct for the cell $Zn|Zn^{2+} \parallel Cu^{2+}|Cu$?

What happens during the discharge of a lead storage battery?

In which of the following cases a chemical reaction is possible?

Which of the following reactions occurs at the cathode during the charging of a lead storage battery?

$A$ solution containing $1 \ mol \ L^{-1}$ of each $Cu(NO_3)_2, AgNO_3, Hg_2(NO_3)_2$ and $Mg(NO_3)_2$ is being electrolysed using inert electrodes. The standard reduction potentials are $E^0_{Ag^{+}/Ag} = +0.80 \ V, E^0_{Hg_2^{2+}/Hg} = +0.79 \ V, E^0_{Cu^{2+}/Cu} = +0.34 \ V, E^0_{Mg^{2+}/Mg} = -2.37 \ V$. With increasing voltage,the sequence of deposition of metals on the cathode will be:

The standard Gibbs free energy change ($\Delta G^{\circ}$ in $kJ \, mol^{-1}$),in a $Daniell$ cell $(E^{\circ}_{cell} = 1.1 \, V)$,when $2 \, moles$ of $Zn_{(s)}$ is oxidised at $298 \, K$,is closest to