Which of the following statements is incorrect?
- AThe rate law for any reaction cannot be determined experimentally.
- BComplex reactions have fractional order.
- CBimolecular reactions involve simultaneous collision between two species.
- DMolecularity is only applicable for elementary reactions.
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Which one of the following is wrong about molecularity of a reaction?
For the reaction $A_2 + B_2 \to 2AB$,the experimental data is given below. Determine the order of the reaction.
Experiment No. $[A_2] \text{ (M)}$ $[B_2] \text{ (M)}$ Rate $(M \cdot s^{-1})$ $1$ $0.1$ $0.1$ $1.6 \times 10^{-4}$ $2$ $0.1$ $0.2$ $3.2 \times 10^{-4}$ $3$ $0.2$ $0.1$ $3.2 \times 10^{-4}$
| Experiment No. | $[A_2] \text{ (M)}$ | $[B_2] \text{ (M)}$ | Rate $(M \cdot s^{-1})$ |
| $1$ | $0.1$ | $0.1$ | $1.6 \times 10^{-4}$ |
| $2$ | $0.1$ | $0.2$ | $3.2 \times 10^{-4}$ |
| $3$ | $0.2$ | $0.1$ | $3.2 \times 10^{-4}$ |
Medium
View SolutionFor which type of reactions,order and molecularity have the same value?
Easy
View SolutionFor the hypothetical reaction $2X + G \to Q + 2M$,the rate expression is $\frac{d[Q]}{dt} = k[X]^2$. Which of the following is the most likely mechanism?
Difficult
View SolutionThe reaction $N_2O_5$ (in $CCl_4$ solution) $\to 2NO_2$ (solution) $+ \frac{1}{2}O_{2(g)}$ is of first order in $N_2O_5$ with rate constant $6.2 \times 10^{-1} \, s^{-1}$. What is the value of the rate of reaction when $[N_2O_5] = 1.25 \, mol \, L^{-1}$?
Easy
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