Which of the following statements is incorrect?

  • A
    For elementary reactions,the order of reaction and molecularity are identical.
  • B
    For the rate-determining step,the order and molecularity are identical.
  • C
    $A$ catalyst does not affect $\Delta H$ (heat of reaction) of a chemical reaction.
  • D
    The activation energy of a reaction decreases with an increase in temperature.

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The rate of the process doubles with every $10 \ K$ increase in temperature. When the temperature is increased from $303 \ K$ to $353 \ K$,how much will the rate of the process increase?

Energy of activation of a reactant is reduced by

From the given data for the reaction $H_2 + I_2 \rightarrow 2HI$,calculate the activation energy $(E_a)$:
$T_1 = 769 \ K, \ 1/T_1 = 1.3 \times 10^{-3} \ K^{-1}, \ \log_{10} K_1 = 2.9$
$T_2 = 667 \ K, \ 1/T_2 = 1.5 \times 10^{-3} \ K^{-1}, \ \log_{10} K_2 = 1.1$

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For the reaction $C_2H_5I + OH^- \rightarrow C_2H_5OH + I^-$,the rate constants at $30^\circ C$ and $60^\circ C$ are $0.325$ and $6.735 \ L \ mol^{-1} \ s^{-1}$ respectively. The value of activation energy $(E_a)$ is .......... calories.

Explain the effect of an increase in temperature on the rate of reaction and the rate constant.

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