Which of the following statements is not correct?

  • A
    $\Delta G^{\circ}$ is an extensive property.
  • B
    $E^{\circ}_{\text{cell}}$ is an intensive property.
  • C
    For a chemical reaction to be spontaneous, $\Delta G$ must be negative.
  • D
    Electrical work is equal to $\Delta G$.

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Match the column $I$ with column $II$ and mark the appropriate choice.
Column $I$Column $II$
$A$. Kohlrausch law$i$. $\Lambda _{m}^o = \nu _+ \lambda _+^o + \nu _- \lambda _-^o$
$B$. Molar Conductivity$ii$. $\Lambda _m = \frac{\kappa \times 1000}{M}$
$C$. Degree of Dissociation$iii$. $\alpha = \frac{\Lambda _m}{\Lambda _m^o}$
$D$. Dissociation Constant$iv$. $K_a = \frac{C\alpha ^2}{1 - \alpha}$

Calculate the $K_C$ and $\Delta G^o$ for the chemical reaction :
$Ni_{(s)} + 2Ag_{(aq)}^{+} \to Ni_{(aq)}^{2+} + 2Ag_{(s)}$ $ [E^o = 1.05 \, V] $

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What is a weak electrolyte? Explain the relation between the concentration of a weak electrolyte and molar conductivity with a suitable graph.

In a fuel cell,methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is
$CH_3OH_{(l)} + \frac{3}{2} O_{2(g)} \rightarrow CO_{2(g)} + 2H_2O_{(l)}$
At $298 \ K$,standard Gibbs energies of formation for $CH_3OH_{(l)}$,$H_2O_{(l)}$,and $CO_{2(g)}$ are $-166.2$,$-237.2$,and $-394.4 \ kJ \ mol^{-1}$ respectively. If the standard enthalpy of combustion of methanol is $-726 \ kJ \ mol^{-1}$,the efficiency of the fuel cell will be .......... $\%$.

If the $\Delta G^o$ for the cell reaction $AgCl_{(s)} + \frac{1}{2} H_{2(g)} \rightarrow Ag_{(s)} + H^+ + Cl^-$ is $-21.52 \, kJ$,what will be the $\Delta G^o$ for the reaction $2AgCl_{(s)} + H_{2(g)} \rightarrow 2Ag_{(s)} + 2H^+ + 2Cl^-$ (in $, kJ$)?

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