Which of the following will have the lowest vapour pressure?

  • A
    $0.1 \ M \ KCl$ solution
  • B
    $0.1 \ M$ urea solution
  • C
    $0.1 \ M \ Na_2SO_4$ solution
  • D
    $0.1 \ M \ K_4[Fe(CN)_6]$ solution

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At $30^\circ C$,liquid $A$ and $B$ form an ideal solution. The total vapor pressure of a solution containing $1 \ mol$ of $A$ and $2 \ mol$ of $B$ is $250 \ mm \ Hg$. The total vapor pressure becomes $300 \ mm \ Hg$ when $1 \ mol$ more of $A$ is added to the first solution. What are the vapor pressures of pure $A$ and $B$ at the same temperature?

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