Which one is the most likely structure of $CrCl_3 \cdot 6H_2O$ if $1/3$ of total chlorine of the compound is precipitated by adding $AgNO_3$ to its aqueous solution?

  • A
    $[Cr(H_2O)_6]Cl_3$
  • B
    $[Cr(H_2O)_3Cl_3] \cdot 3H_2O$
  • C
    $[CrCl_2(H_2O)_4]Cl \cdot 2H_2O$
  • D
    $[CrCl(H_2O)_5]Cl_2 \cdot H_2O$

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The stepwise formation of $[Cu(NH_{3})_{4}]^{2+}$ is given below:
$Cu^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})]^{2+} \quad K_{1}$
$[Cu(NH_{3})]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{2}]^{2+} \quad K_{2}$
$[Cu(NH_{3})_{2}]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{3}]^{2+} \quad K_{3}$
$[Cu(NH_{3})_{3}]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{4}]^{2+} \quad K_{4}$
The values of stability constants $K_{1}, K_{2}, K_{3}$ and $K_{4}$ are $10^{4}, 1.58 \times 10^{3}, 5 \times 10^{2}$ and $10^{2}$ respectively. The overall equilibrium constant for dissociation of $[Cu(NH_{3})_{4}]^{2+}$ is $x \times 10^{-12}$. The value of $x$ is ...............
(Rounded off to the nearest integer)

Which complex is formed when an aqueous solution of $NH_3$ is added to a $CuSO_4$ solution,resulting in a deep blue color?

Which of the following is the correct increasing order of ligand field strength according to the spectrochemical series?

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