Which one of the following complexes will con | vedclass

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(D) The consumption of $AgNO_3$ depends on the number of ionizable $Cl^-$ ions present outside the coordination sphere.$Na_2[CrCl_5(H_2O)]$ provides $

Vedclass · Accepted Answer

$[Cr(H_2O)_6]Cl_3$

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(D) The consumption of $AgNO_3$ depends on the number of ionizable $Cl^-$ ions present outside the coordination sphere.$Na_2[CrCl_5(H_2O)]$ provides $0$ ionizable $Cl^-$ ions.$Na_3[CrCl_6]$ provides $0$ ionizable $Cl^-$ ions.$[Cr(H_2O)_5Cl]Cl_2$ provides $2$ ionizable $Cl^-$ ions.$[Cr(H_2O)_6]Cl_3$ provides $3$ ionizable $Cl^-$ ions.Since $[Cr(H_2O)_6]Cl_3$ furnishes the highest number of $Cl^-$ ions ($3$ moles per mole of complex),it will consume the most equivalents of $AgNO_3$.

Which one of the following complexes will consume more equivalents of aqueous solution of $AgNO_3$?

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