Which one of the following graphs between molar conductivity $\left(\Lambda_m\right)$ versus $\sqrt{C}$ is correct?

  • A
    Option A
  • B
    Option B
  • C
    Option C
  • D
    Option D

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Solutions $A$,$B$,and $C$ of the same strong electrolyte offered resistances of $50 \ \Omega$,$100 \ \Omega$,and $150 \ \Omega$ in a given conductivity cell. The resistance observed if they are mixed in a volume proportion which is the reciprocal of their resistances and tested in the same conductivity cell would be ............. $\Omega$.

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Tollen's reagent is used for the detection of aldehyde. When a solution of $AgNO_3$ is added to glucose with $NH_4OH$,gluconic acid is formed.
$Ag^{+} + e^{-} \rightarrow Ag ; E^{\circ}_{red} = 0.8 \ V$
$C_6H_{12}O_6 + H_2O \rightarrow C_6H_{12}O_7 + 2H^{+} + 2e^{-} ; E^{\circ}_{oxd} = -0.05 \ V$
$Ag(NH_3)_2^{+} + e^{-} \rightarrow Ag_{(s)} + 2NH_3 ; E^{\circ}_{red} = 0.337 \ V$
[Use $2.303 \times \frac{RT}{F} = 0.0592$ and $\frac{F}{RT} = 38.92$ at $298 \ K$]
$1.$ $2Ag^{+} + C_6H_{12}O_6 + H_2O \rightarrow 2Ag_{(s)} + C_6H_{12}O_7 + 2H^{+}$. Find $\ln K$ of this reaction.
$(A) \ 66.13 \quad (B) \ 58.38 \quad (C) \ 28.30 \quad (D) \ 46.29$
$2.$ When ammonia is added to the solution,$pH$ is raised to $11$. Which half-cell reaction is affected by $pH$ and by how much?
$(A) E_{oxd}$ will increase by a factor of $0.65 \ V$ from $E^{\circ}_{oxd}$
$(B) E_{oxd}$ will decrease by a factor of $0.65 \ V$ from $E^{\circ}_{oxd}$
$(C) E_{red}$ will increase by a factor of $0.65 \ V$ from $E^{\circ}_{red}$
$(D) E_{red}$ will decrease by a factor of $0.65 \ V$ from $E^{\circ}_{red}$
$3.$ Ammonia is always added in this reaction. Which of the following must be incorrect?
$(A) NH_3$ combines with $Ag^{+}$ to form a complex.
$(B) Ag(NH_3)_2^{+}$ is a stronger oxidising reagent than $Ag^{+}$.
$(C)$ In absence of $NH_3$,silver salt of gluconic acid is formed.
$(D) NH_3$ has affected the standard reduction potential of glucose/gluconic acid electrode.
Give the answer for questions $1, 2$ and $3$.

Copper from copper sulphate solution can be displaced by .............. The standard reduction potentials of some electrodes are given below:
$E^o (Fe^{2+}, Fe) = -0.44 \ V$
$E^o (Zn^{2+}, Zn) = -0.76 \ V$
$E^o (Cu^{2+}, Cu) = +0.34 \ V$
$E^o (Cr^{2+}, Cr) = -0.74 \ V$
$E^o (H^{+}, 1/2H_2) = 0.00 \ V$

Which of the following statements is not correct?

Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.

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