Which one of the following is expected to exhibit optical isomerism $(en = \text{ethylenediamine})$?

  • A
    $cis-[Pt(NH_3)_2Cl_2]$
  • B
    $trans-[Co(en)_2Cl_2]^+$
  • C
    $trans-[Pt(NH_3)_2Cl_2]$
  • D
    $cis-[Co(en)_2Cl_2]^+$

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Which of the following complexes shows optical isomerism?

The correct match of the complexes with their structure and magnetic property is:
Complex Structure and magnetic property
$i$. $NiCl_4^{2-}$ $p$. tetrahedral and diamagnetic
$ii$. $Ni(CO)_4$ $q$. tetrahedral and paramagnetic
$iii$. $PtCl_4^{2-}$ $r$. square planar and diamagnetic
$iv$. $Ni(CN)_4^{2-}$ $s$. square planar and paramagnetic

The correct structures of trans-$[NiBr_{2}(PPh_{3})_{2}]$ and meridional-$[Co(NH_{3})_{3}(NO_{2})_{3}]$,respectively,are

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