Which one of the following is a non-ideal solution?

  • A
    Benzene + toluene
  • B
    $n$-hexane + $n$-heptane
  • C
    Ethyl bromide + ethyl iodide
  • D
    $CCl_4 + CHCl_3$

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If vapour pressures of pure liquids $A$ and $B$ are $300$ and $800 \, torr$ respectively at $25 \, ^{\circ}C$. When these two liquids are mixed at this temperature to form a solution in which mole percentage of $B$ is $92$,then the total vapour pressure is observed to be $0.95 \, atm$. Which of the following is true for this solution?

$A$ liquid solution is formed by mixing $10 \, moles$ of aniline and $20 \, moles$ of phenol at a temperature where the vapour pressure of pure liquid aniline and phenol are $90 \, mmHg$ and $87 \, mmHg$ respectively. The possible vapour pressure of the solution at that temperature is ............. $mmHg$.

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