Which one of the following non-ideal solutions shows negative deviation?

$A$ mixture of ethanol and acetone shows positive deviation from Raoult's law because:

$A$ liquid solution is formed by mixing $10 \, moles$ of aniline and $20 \, moles$ of phenol at a temperature where the vapour pressure of pure liquid aniline and phenol are $90 \, mmHg$ and $87 \, mmHg$ respectively. The possible vapour pressure of the solution at that temperature is ............. $mmHg$.

Assuming the formation of an ideal solution,determine the boiling point of a mixture containing $1560 \ g$ benzene (molar mass $= 78 \ g/mol$) and $1125 \ g$ chlorobenzene (molar mass $= 112.5 \ g/mol$) against an external pressure of $1000 \ torr$ using the provided graph. (in $^{\circ}C$)

At $300 \ K$,the vapour pressures of $A$ and $B$ liquids are $500 \ mm \ Hg$ and $400 \ mm \ Hg$ respectively. Equal moles of $A$ and $B$ are mixed to form an ideal solution. The mole fraction of $A$ and $B$ in the vapor state is respectively:

An aqueous solution of hydrochloric acid: