Which one of the following statements is false?

  • A
    Raoult's law for a mixture of two liquids states that the vapour pressure of a component over a solution is proportional to its mole fraction.
  • B
    The osmotic pressure $(\pi)$ of a solution is given by the equation $\pi = iCRT$,where $C$ is the molarity of the solution.
  • C
    The correct order of osmotic pressure for $0.02 \ M$ aqueous solution of each compound is $SrCl_2 > NaCl > HCOOH > Sucrose$.
  • D
    Two sucrose solutions of the same molality prepared in different solvents will have the same freezing point depression.

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If ethanol dissolves in water,then which of the following would be done?

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Match List-$I$ with List-$II$.
List-$I$ List-$II$
$A$. van't Hoff factor,$i$ $I$. Cryoscopic constant
$B$. $k_{f}$ $II$. Isotonic solutions
$C$. Solutions with same osmotic pressure $III$. $\frac{\text{Normal molar mass}}{\text{Abnormal molar mass}}$
$D$. Azeotropes $IV$. Solutions with same composition of vapour above it

Choose the correct answer from the options given below:

Elevation in boiling point for $1.5 \, m$ solution of glucose in water is $4 \, K$. The depression in freezing point for $4.5 \, m$ solution of glucose in water is $4 \, K$. The ratio of molal elevation constant to molal depression constant $(K_{b} / K_{f})$ is $....$

The osmotic pressure of a solution is directly proportional to

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