Which technique among the following is most appropriate for the separation of a mixture of $100 \ mg$ of $p-$nitrophenol and picric acid?

In the given $TLC$ plate,the distances of spots $A$ and $B$ from the base line are $4 \ cm$ and $6 \ cm$,respectively. The distance moved by the solvent front from the base line is $8 \ cm$. If the $R_f$ value of $B$ is $x \times 10^{-1}$ times that of $A$,find the value of $x$.

State True or False for the following statements:
$(i)$ The volatile liquid is purified by fractional distillation or simple distillation.
$(ii)$ Two liquids are separated by fractional distillation.
$(iii)$ Liquids with a small difference in boiling points are separated by fractional distillation.
$(iv)$ Liquids with a large difference in boiling points are separated by fractional distillation.

Which purification method is generally used for a high boiling organic liquid compound,which decomposes below its boiling point?

Match List-$I$ with List-$II$.

List-$I$ (Purification technique)	List-$II$ (Mixture of organic compounds)
$(A)$ Distillation (simple)	$(I)$ Diesel + Petrol
$(B)$ Fractional distillation	$(II)$ Aniline + Water
$(C)$ Distillation under reduced pressure	$(III)$ Chloroform + Aniline
$(D)$ Steam distillation	$(IV)$ Glycerol + Spent-lye

Choose the correct answer from the options given below $:$

Fill in the Blanks :
$(1)$ The steam distillation of $.......$ liquid is done and it is boiled at $.........$ temperature.
$(2)$ $.........$ and $........$ used to reduce pressure in distillation under reduced pressure.
$(3)$ In steam distillation the equation of total vapour pressure is $P = p_1 + p_2$ where $p_1$ is more than $...........$
$(4)$ $.........$ apparatus is used in differential extraction.