While titrating a dilute $HCl$ solution with an aqueous $NaOH$ solution,which of the following will not be required?

  • A
    Clamp and phenolphthalein
  • B
    Pipette and distilled water
  • C
    Burette and porcelain tile
  • D
    Bunsen burner and measuring cylinder

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$5.00 \ mL$ of $0.10 \ M$ oxalic acid solution taken in a conical flask is titrated against $NaOH$ from a burette using phenolphthalein indicator. The volume of $NaOH$ required for the appearance of permanent faint pink color is tabulated below for five experiments. What is the concentration,in molarity,of the $NaOH$ solution?
$Exp. \ No.$ $Vol. \ of \ NaOH \ (mL)$
$1$ $12.5$
$2$ $10.5$
$3$ $9.0$
$4$ $9.0$
$5$ $9.0$

In a titration experiment,$10 \, mL$ of an $FeCl_{2}$ solution consumed $25 \, mL$ of a standard $K_{2}Cr_{2}O_{7}$ solution to reach the equivalence point. The standard $K_{2}Cr_{2}O_{7}$ solution is prepared by dissolving $1.225 \, g$ of $K_{2}Cr_{2}O_{7}$ in $250 \, mL$ water. The concentration of the $FeCl_{2}$ solution is closest to $..... \, N$
[Given : molecular weight of $K_{2}Cr_{2}O_{7} = 294 \, g \, mol^{-1}$]

$10.0 \, mL$ of $Na_{2}CO_{3}$ solution is titrated against $0.2 \, M \, HCl$ solution. The following titre values were obtained in $5$ readings.
$4.8 \, mL, 4.9 \, mL, 5.0 \, mL, 5.0 \, mL$ and $5.0 \, mL$
Based on these readings,and convention of titrimetric estimation,the concentration of $Na_{2}CO_{3}$ solution is .... $mM$.
(Round off to the nearest integer)

Temporary hardness in tap water is measured in terms of parts of $CaCO_3$ per $10^6$ parts of water. If $500 \ mL$ of hard water containing $Ca(HCO_3)_2$ was titrated against $\frac{1}{20} \ M \ H_2SO_4$ solution in the presence of a methyl orange indicator,and it required $40 \ mL$ of titrant,then the temporary hardness in the tap water is .............. $ppm$.

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In a conductometric titration,a small volume of titrant of higher concentration is added stepwise to a larger volume of titrate of much lower concentration,and the conductance is measured after each addition.
The limiting ionic conductivity ( $\Lambda ^0$ ) values (in $mS \ m ^2 \ mol ^{-1}$ ) for different ions in aqueous solutions are given below:
Ions$Ag ^{+}$$K ^{+}$$Na ^{+}$$H ^{+}$$NO _3^{-}$$Cl ^{-}$$SO _4^{2-}$$OH ^{-}$$CH _3COO ^{-}$
$\Lambda _0$$6.2$$7.4$$5.0$$35.0$$7.2$$7.6$$16.0$$19.9$$4.1$

For different combinations of titrates and titrants given in List-$I$,the graphs of 'conductance' versus 'volume of titrant' are given in List-$II$.
List-$I$List-$II$
$(P)$ Titrate: $KCl$,Titrant: $AgNO _3$$(1)$ Graph showing initial decrease then increase
$(Q)$ Titrate: $AgNO _3$,Titrant: $KCl$$(2)$ Graph showing sharp decrease then sharp increase
$(R)$ Titrate: $NaOH$,Titrant: $HCl$$(3)$ Graph showing slight decrease then increase
$(S)$ Titrate: $NaOH$,Titrant: $CH _3COOH$$(4)$ Graph showing continuous increase
$(5)$ Graph showing decrease then constant

Match each entry in List-$I$ with the appropriate entry in List-$II$ and choose the correct option.

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