Would you expect the second electron gain enthalpy of $O$ to be positive,more negative,or less negative than the first? Justify your answer.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(A) When an electron is added to an $O$ atom to form an $O^{-}$ ion,energy is released. Thus,the first electron gain enthalpy of $O$ is negative.
$O_{(g)} + e^{-} \longrightarrow O_{(g)}^{-} \quad \Delta_{eg}H = -141 \ kJ \ mol^{-1}$
On the other hand,when an electron is added to an $O^{-}$ ion to form an $O^{2-}$ ion,energy must be supplied to overcome the strong electrostatic repulsion between the incoming electron and the negatively charged $O^{-}$ ion. Thus,the second electron gain enthalpy of $O$ is positive.
$O_{(g)}^{-} + e^{-} \longrightarrow O^{2-}_{(g)} \quad \Delta_{eg}H = +780 \ kJ \ mol^{-1}$

Explore More

Similar Questions

The work function of nickel is $5 \text{ eV}$. When light of wavelength $2000 \text{ \AA}$ falls on it, it emits photoelectrons. The potential difference necessary to stop the fastest electrons emitted is (given $h = 6.67 \times 10^{-34} \text{ J-s}$): (in $\text{ V}$)

Two rain drops reach the earth with different terminal velocities having ratio $9:4$. Then the ratio of their volumes is

Under the influence of a uniform magnetic field,a charged particle is moving in a circle of radius $R$ with constant speed $v$. The time period of the motion

If in a $\triangle ABC$,$r_1=2$,$r_2=3$ and $r_3=6$,then $a$ equals to

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo