Write a test to differentiate between pentan$-2-$one and pentan$-3-$one.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
Pentan$-2-$one contains a $CH_3CO-$ group,therefore it gives a positive iodoform test with $I_2/NaOH$,forming a yellow precipitate of iodoform $(CHI_3)$.
Pentan$-3-$one does not contain a $CH_3CO-$ group,therefore it does not give a positive iodoform test.
Reaction:
$CH_3CH_2CH_2COCH_3 + 3I_2 + 4NaOH \rightarrow CH_3CH_2CH_2COONa + CHI_3 \text{ (yellow ppt)} + 3NaI + 3H_2O$
$CH_3CH_2COCH_2CH_3 + I_2/NaOH \rightarrow \text{No reaction}$

Explore More

Similar Questions

The best reagent to convert $pent-3-en-2-ol$ into $pent-3-yn-2-one$ is

The product in the given reaction is:

Aldol condensation reaction is

Which of the following does not effect the transformation shown below?
$R_2C=O \rightarrow R_2CH_2$

$A$ compound $A$ has the molecular formula $C_2Cl_3OH$. It reduces Fehling's solution and on oxidation,it gives a monocarboxylic acid $B$. Compound $A$ is also obtained by the reaction of ethanol with chlorine. What is $A$?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo